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Name : Ahmad Daraosheh

Academic Rank: Assistant Professor

Administrative Position : Faculty Academic Member

Office 7117       Ext No 7117

Email :

Specialization: Organic Chemistry

Graduate Of: Friedrich Schiller University-Jena

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    Jordan University of Science and Technology
    Jordan University of Science and Technology
    Friedrich Schiller University-Jena

  • Journal Paper

      Mohammad K. Harb, Ahmad Daraosheh, Helmar G?rls, Elliott R. Smith, G. Joel Meyer, Matthew T. Swenson, Takahiro Sakamoto, Richard S. Glass, Dennis L. Lichtenberger, Dennis H. Evans, Mohammad El-khateeb, " Effects of Alkane Linker Length and Chalcogen Character in [FeFe]-Hydrogenase Inspired Compounds " , "Heteroatom Chemistry",Vol.,No., Wiley Periodicals, Inc., , 09/01/2014 Abstract:
      containing compounds catalyze proton reduction at potentials, which are 0.23 V less negative than the Se-containing compounds in this study.

      Ahmad Q. Daraosheh, Ulf-Peter Apfel, Helmar G?rls, Christian Friebe,Ulrich S. Schubert, Mohammad El-khateeb, Grzegorz Mloston, and Wolfgang Weigand, " New Approach to [FeFe]-Hydrogenase Models Using Aromatic Thioketone " , "European Journal of Inorganic Chemistry",Vol.,No., Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, , 12/12/2011 Abstract:
      The reactions of triiron dodecacarbonyl with thiobenzophenone (2a) and 9H-thioxanthene-9-thione (2b) were investigated under different conditions. In the case of a 1:1 molar ratio of triiron dodecacarbonyl and 2a or 2b, the ortho-metallated complexes [Fe2(CO)6{μ,κ,S,SCH(C6H5)C6H4-η2}] (3a) and [Fe2(

      Ahmad Q. Daraosheh, Helmar G?rls, Mohammad El-khateeb, Grzegorz Mloston,v and Wolfgang Weigand, " Reactions of Selected Aromatic Thioketones with Dodecarbonyltriiron " , "European Journal of Inorganic Chemistry",Vol.,No., Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, , 12/09/2010 Abstract:
      odecacarbonyltriiron reacts with 3,3,5,5-tetraphenyl-1,2,4-trithiolanes (1e) to give the ortho-metalated complex Fe2(CO)6[κ,μ-S,η2-(C13H10S)] (9a), complexes of the type (Ph2C)S2Fe2(CO)6 and the well known trinuclear complex Fe3S2 (CO)9 as by-products. Complex 9a can also be obtained from the reacti

      Ahmad Q. Daraosheh, Mohammad K. Harb, Jochen Windhager, Helmar G?rls, Mohammad El-khateeb and Wolfgang Weigand, " ٍSubstitution Reactions at [FeFe] Hydrogenase Models Containing [2Fe3S] Assembly by Phosphine or Phosphite Ligands " , "Organometallics",Vol.,No., American Chemical Society, , 10/16/2009 Abstract:
      [2Fe3S] complex 1, which is related to the active site of [FeFe] hydrogenases, substitution studies of CO ligands by phosphite and phosphine ligands at compound Fe2(μ-S2(C3H6)2S-μ)(CO)5 (1) have been investigated. The reaction of 1 with 1 equiv of trimethylphosphite gave the kinetically controlled p Download

      Mohammad K. Harb, Jochen Windhager, Ahmad Daraosheh, Helmar G?rls, L. Tori Lockett, Noriko Okumura,[b] Dennis H. Evans, Richard S. Glass,Dennis L. Lichtenberger, Mohammad El-khateeb, and Wolfgang Weig, " Phosphane- and Phosphite-Substituted Diiron Diselenolato Complexes as Models for [FeFe]-Hydrogenases " , "European Journal of Inorganic Chemistry",Vol.,No., Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009, , 06/30/2009 Abstract:
      The displacement of terminal CO ligands in Fe2(μ-Se2C3H5CH3)(CO)6 (1) by triphenylphosphane, trimethyl phosphite, and bis(diphenylphosphanyl)ethane (dppe) ligands is investigated. Treatment of 1 with 1 equiv. of triphenylphosphane afforded Fe2(μ-Se2C3H5CH3)(CO)5(PPh3) (2). The mono- and disubstitute Download

      Khalil J. Asali, Mohammad El-khateeb, Ahmad Daraosheh, " Bimetallic Group 6 Tricarbonyls Containing Rigid Backbone Chelating Ligands Symmetrically Bridged by Bis(diphenylphosphino)alkane " , "Jordan Journal of Chemistry",Vol.,No., Yarmouk University, Irbid, Jordan, , 06/04/2009

      Hassan Abul-Futouh a, Ahmad Q. Daraosheh , Jochen Windhager, Helmar G?rls , Wolfgang Weig, " Synthesis and characterization of [FeFe]-hydrogenase models mediated by a 1,2,4-trithiolane derivative: Insight into molecular structures and electrochemical characteristics " , "Polyhedron",Vol.174,No., ُُELSEVIER, Amman/Jordan, 09/25/2019 Abstract:
      In this report two diiron hexacarbonyl complexes containing sulphur-rich heterocycles have been prepared as [FeFe]-hydrogenase mimics. These two complexes are obtained from the reaction of Fe3(CO)12 with 3,11-dibenzyl-7,14,15-trithia-3,11-diazadispiro[]pentadecane. They have been characte
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